He lost consciousness while praying
Once an arrow stuck in the feet of Ali. It could not be taken out because of the intensity of the pain felt. When Ali stood up in prayers, he was so much absorbed in the devotional exercise that the surgeon pulled out the arrow without Ali feeling any pain.
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"When a person dies, his works end, except for three: ongoing charity, knowledge that is benefited from, and a righteous child who prays for him."
Prophet Mohammed (PBUH)
"The best of what a man leaves behind are three: a righteous child who supplicates for him, ongoing charity the reward of which reaches him, and knowledge that is acted upon after him."
Sunan Ibn Mājah
"Every day two angels come down from Heaven and one of them says, 'O Allah! Compensate every person who spends in Your Cause,' and the other (angel) says, 'O Allah! Destroy every miser.'"
Sahih Bukhari